Product ID:GENESOLV D SOLVENT (VARIOUS GRADES)
MSDS Date:10/01/1985
FSC:6850
NIIN:00-983-0282
MSDS Number: BGBLG

Emergency Phone: 201-455-2000

Cage: 1L168

Telephone: 201-455-4414

Cage: 1L164

1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON 113) (SARA

CAS: 76-13-1

RTECS: KJ4000000

Fraction By Weight: 100%

OSHA PEL 1000PPM/1250STEL

ACGIH TLV: 1000PPM/1250STEL9192

LD50 LC50 Mixture:LD50 (RAT): 43 G/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Health Hazards Acute and Chronic:INHAL:DROWSINESS,LOSS OF
CONCENTRATION,CARDIAC EFFECTS. INGEST: DISCOMFORT&SAME SYMPTOMS AS
INHAL. EYE & SKIN:IRRITANT W/DEFATTING
Effects of Overexposure:THIS MATERIAL IS LOW IN TOXICITY, IT IS AN
ANESTHETIC & INHALATION ON HIGH CONCENTRATIONS CAN PRODUCE
ASPHYXIATION. AT 2500 PPM IN AIR IT INTERFERS WITH PHYCHOLOGICAL
AND PHYCHOMOTOR FUNCTIONS. EXPRES SED AS EXCITEMENT AND
INCOORDINATION. CARDIAC ARRHYTHMIA IS INDICATED AT HIGH
CONCENTRATIONS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MFR.

First Aid:INHAL:RMV PATIENT TO FRESH AIR. GIVE CPR IF BREATHING HAS
STOPPED. GIVE OXYGEN AS REQD. GET MEDICAL ATTN. DO NOT GIVE
ADRENALIN (EPINEPHRINE). EYE:FLUSH W/LG AMTS OF WATER. IF SMPTOMS
PERSISTS, CONSUL T PHYSICIAN. SKIN: WASH W/WATER. INGEST: INDUCE
VOMITING IMMEDIATELY BY GIVING 2 GLASSES OF WATER & TOUCHING FINGER
TO BACK OF THROAT. GET MEDICAL ATTN.

Flash Point:NOT FLAMMABLE
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS
APPROVED BY NIOSH. USE WATER SPRAY TO KEEP CONTAINERS COOL, TO KEEP
SPILLAGE AWAY FROM FIRE & HEAT & TO KNOCK DOWN VAPOR
Unusual Fire/Explosion Hazard:SEE MATERIALS TO AVOID. DECOMPOSES AT
TEMP ABOVE 250F T HALOGENS, HALOGEN ACIDS, AND POSSIBLY CARBONYL
HALIDES, SUCH AS PHOSGENE.

Spill Release Procedures:EVACUATE UNPROTECTED PERSONNAL. PROTECTED
PERSONNEL RMV FLAMES & SHUT OFF LAK. ABSORB LIQUID W/COML
ABSORBENT,SHOVEL INTO METAL DRUMS & CLOSE. LG AMTS: DIKE UP WITH
COML ABSORBENT & PUMP INTO DRUMS.
Neutralizing Agent:NONE REQD

Handling and Storage Precautions:STORE IN COOL, WELL VENTILATED AREA OF
LOW FIRE RISK. PROTECT CONTAINERS FROM PHYSICAL DAMAGE AND KEEP
CLOSED.
Other Precautions:AVOID BREATHING VAPOR, LIQUID CONTACT W/EYE, SKIN OR
CLOTHING.

Respiratory Protection:NONE REQUIRED FOR NORMALLY VENTED WORK
SITUATIONS. FOR NON-VENTILATED SITUATIONS, USE SCBA OR SUPPLIED AIR
RESPIRATOR. FOR ESCAPE:SCBA OR GAS MASK W/ORGANIC VAPOR CANISTER.
ALL RESPIRATORS MUST BE NIO SH APPROVED.
Ventilation:LOCAL AT FILLING ZONES & OPERATING SPACES WHERE LEAKING IS
PROBABLE. MECHANICAL(GEN) IS OK FOR OTHER OPER&STORAGE AREAS.
Protective Gloves:PVA OR NEOPRENE FOR PROLONGED CONTACT
Eye Protection:CHEMICAL SAFETY GOGGLES FOR LIQ CONTACT.
Other Protective Equipment:PROTECTIVE CLOTHING OF PVA OR NEOPRENE TO
PREVENT REPEATED OR PROLONGED CONTACT.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING&BEFORE EATING OR
SMOKING.
Supplemental Safety and Health
DO NOT SMOKE IN AREA WHERE FUMES MAY BE PRESENT. TOXIC GASES MAY BE
FOREMD.

HCC:N1
Boiling Pt:B.P. Text:117.7F,48C
Melt/Freeze Pt:M.P/F.P Text:-33.7F,-37C
Decomp Temp:Decomp Text:>250F,>121C
Vapor Pres:284
Vapor Density:6.5
Spec Gravity:1.57
Evaporation Rate & Reference:1.3 (ETHER=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR COLORLESS LIQUID WITH ETHEREAL ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
CHEMICALLY ACTIVE METALS SUCH AS
ALMINUM,BARIUM,LIGHIUM,TITANIUM,CALCIUM,MAGNESIUM,ZINC & BERYLLIUM
IN POWDERED FORM.
Stability Condition to Avoid:AVOID LIGHTED CIGARETTES, FLAMES, HOT
SPOTS, WELDING.
Hazardous Decomposition Products:HALOGENS, HALOGEN ACIDS, AND POSSIBLY
CARBONYL HALIDES, SUCH AS PHOSGENE.

Waste Disposal Methods:DISPOSE I/A/W LOCAL, STATE AND FEDERAL
REGULATIONS. IT IS ANTICIPATED THAT MATERIAL SOLD UNDER THE
GENETRON NAME WILL NOT BE USED AS A SOLVENT. THEREFORE THE RCRA
"SPENT HALOGENATED SOLVENT" CLASSIFIC ATION WILL NOT APPLY. SEE
PN/IND A FOR GENESOLV D.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.